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What is Diamond?
Where is it found?The most famous diamond bearing country is South Africa. The first diamond was reported in 1866. By 1869 an 83.5 carat diamond had been found and was named The Star of Africa. It was subsequently cut into a pear shape brilliant weighing 47.74 carats. The Golconda area of Southern India has been the source of some famous diamonds such as the Koh-i-nor (mountain of light 186cts cut to 108.92 cts and now in the Tower of London) and Jehangir. Diamond is widespread in Brazil, most stones being small but of good gem quality. Alluvial diamonds have been found in most states of the USA. White and fancy coloured diamonds such as pinks and pinkish browns are mined at Argyle in North Western Australia. Other important producers are Russia, now the fourth largest producer, and China.
By weight the top ten producers in 1994 were:
Australia
Zaire
Botswana
Russia
South Africa
South America
Angola
Namibia
Ghana
Guinea
By Value The top ten were:
Botswana
Russia
South Africa
Zaire
Australia
Namibia
Angola
South America
Guinea
Sierra Leone
Causes Of Colour?The causes of these colours lies at atomic level. Diamond comprises covalently bonded carbon atoms. In pure diamond visible light does not possess enough energy to excite electrons in the bonds and consequently no light is absorbed in the visible band and all the light falling on the diamond is transmitted and refracted back to the eye causing the diamond to appear completely colourless.
However, most diamonds are not perfect. The diamond lattice contains impurities such as nitrogen and the lattice is sometimes defective with a missing atom. This presence of impurities, or more specifically the electrons associated with the impurities, is the cause of colour in the majority of diamonds.
Yellow: Nitrogen is the cause of colour in these diamonds.
Brown: Plastic deformation of the diamond lattice whilst in the earth.
Pink & Mauve: Plastic deformation of the diamond lattice in the upper mantle
region of the earth.
Black: Caused by a vast quantity of dark opaque inclusions.
Blue: Boron impurity in the lattice.
Green: Caused by alpha particle radiation.
Colour Treatments
The rarety and subsequent high value of fancy coloured diamonds has led to the development of artificial colouration of diamonds.
There are two main types:
1 Surface coating to disguise real colour of diamond
This is done by coating the diamond surface with a metal halide in a process similar to that used in producing the rich blue bloom seen on camera lenses. It is easily removed by boiling in acid for a couple of minutes, and is attacked when a working jeweller places a hot diamond in acid as part of the process of sizing a ring for example.
A light enamelling is sometimes applied to the lower pavilion facets to simulate or improve a colour.
2 Alter the body colour
Cyclotron Treatment:
This is a device used to accelerate sub atomic particles such as protons, deuterons (heavy hydrogen), and alpha particles (Helium nucleus mass 4, charge +2e) and smash them into the diamond lattice. The colour produced is from dark green to almost black. The particles are charged and depth penetration is poor, forming a skin. The colour is permanent unless the stone is repolished.
Further heating converts the green to yellow, orange or brown.
Electron Treatment:
Electrons are accelerated in to the diamond, again only skin deep and produce a blue to blue/green colour. heat treatment produces orange-yellow, pink- mauve, and brown.
Gamma Ray:
Not used today due to its slow effects taking months to colour a stone. Produces permanent blue and blueish-green colours.
Neutron Treatment:
This is the most common form of irradiation used today. The diamonds are bombarded in a nuclear reactor and produce permanent green. When heated, yellow, orange, brown, pink and mauve colours may be produced.
Radium:
Produces colours from alpha, beta, and gamma radiation, but is not used as stones are left radioactive.
Evidence of treatment:
If you should ever consider buying a coloured diamond have it checked by a reputable laboratory to ascertain whether the colour is natural or otherwise. The difference in price is vast. A report may also indicate its permanance.
How diamonds are formed?Diamond is formed at great depth in the earth, between 150 and 300 km below the surface and at great temperatures and pressures. By a kind of volcanic eruption the diamonds were pushed up through volcanic pipes of diamond bearing rock such as kimberlite. With gradual erosion kimberlite chimneys were exposed at the earths surface.
Inclusions in Diamond
| Peridotitic (Crystal Form) | Eclogotic (Crystal form) | Epigenetic Inclusions (powder form) | Inclusions of uncertain origin |
| Olivine | Omphacite | Serpentine | Amphibole |
| Enstatite | Garnet | Graphite | Magneteite |
| Diopside | Kyanite | Hematite | Feldspar |
| Garnet | Ilmenite | Goethite | Mica |
| Spinel | Chromite | Kaolinite | |
| Ilmenite | Sulphides | ||
| sulphides | Coesite | ||
| Zircon | Diamond | ||
| Diamond | Ruby | ||
| Rutile |
Diamond Hardness
The Diamond 4 C's